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Synthesis of triarylborane-centered N-heterocyclic carbene cages with tunable photophysical properties.
Zhang, Yi-Fan; Zhang, Ya-Wen; Li, Xin; Sun, Li-Ying; Han, Ying-Feng.
Affiliation
  • Zhang YF; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, Xi'an Key Laboratory of Functional Supramolecular Structure and Materials, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, P. R. China. lysun@nwu.edu.cn.
  • Zhang YW; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, Xi'an Key Laboratory of Functional Supramolecular Structure and Materials, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, P. R. China. lysun@nwu.edu.cn.
  • Li X; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, Xi'an Key Laboratory of Functional Supramolecular Structure and Materials, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, P. R. China. lysun@nwu.edu.cn.
  • Sun LY; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, Xi'an Key Laboratory of Functional Supramolecular Structure and Materials, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, P. R. China. lysun@nwu.edu.cn.
  • Han YF; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, Xi'an Key Laboratory of Functional Supramolecular Structure and Materials, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, P. R. China. lysun@nwu.edu.cn.
Chem Commun (Camb) ; 59(16): 2291-2294, 2023 Feb 21.
Article in En | MEDLINE | ID: mdl-36744641
Triarylborane-based discrete metal-carbene supramolecular cages [M3(1)2](PF6)3 (M = Ag, Au) were synthesized and characterized. The new hexacarbene assemblies show a significant solvatochromic effect in solvents of different polarity. Furthermore, the reversible fluoride binding property of [Au3(1)2](PF6)3 was investigated by UV-vis absorption and fluorescence titrations. This work holds promise for future developments in the area of highly emissive and stimulus-responsive NHC-metal assemblies.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Document type: Article Country of publication: United kingdom
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2023 Document type: Article Country of publication: United kingdom