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Nickel-catalysed enantioselective reaction of secondary phosphine oxides and activated vinylcyclopropanes.
Huang, Zhuo; Liu, Xu-Teng; Cui, Ranran; Zhang, Qing-Wei.
Affiliation
  • Huang Z; Key Laboratory of Precision and Intelligent Chemistry, Department of Chemistry, University of Science and Technology of China, Hefei 230026, People's Republic of China. qingweiz@ustc.edu.cn.
  • Liu XT; Key Laboratory of Precision and Intelligent Chemistry, Department of Chemistry, University of Science and Technology of China, Hefei 230026, People's Republic of China. qingweiz@ustc.edu.cn.
  • Cui R; Key Laboratory of Precision and Intelligent Chemistry, Department of Chemistry, University of Science and Technology of China, Hefei 230026, People's Republic of China. qingweiz@ustc.edu.cn.
  • Zhang QW; Key Laboratory of Precision and Intelligent Chemistry, Department of Chemistry, University of Science and Technology of China, Hefei 230026, People's Republic of China. qingweiz@ustc.edu.cn.
Org Biomol Chem ; 21(15): 3096-3100, 2023 Apr 12.
Article in En | MEDLINE | ID: mdl-36974750
Activated vinylcyclopropanes can form zwitterionic π-allylmetal species in the presence of transition metals and are widely used in organic synthesis. A nickel-catalyzed asymmetric allylation of secondary phosphine oxides with vinylcyclopropanes was described. Tertiary phosphine oxide products could be obtained with up to 91% yield and 92% ee.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Biomol Chem Journal subject: BIOQUIMICA / QUIMICA Year: 2023 Document type: Article Country of publication: United kingdom
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Biomol Chem Journal subject: BIOQUIMICA / QUIMICA Year: 2023 Document type: Article Country of publication: United kingdom