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Boost of Gas Adsorption Kinetics of Covalent Organic Frameworks via Ionic Liquid Solution Process.
Fu, Jie; Liu, Jia-Ying; Zhang, Guo-Hao; Zhu, Qiu-Hong; Wang, Shuang-Long; Qin, Song; He, Ling; Tao, Guo-Hong.
Affiliation
  • Fu J; College of Chemistry, Sichuan University, Chengdu, 610064, China.
  • Liu JY; College of Chemistry, Sichuan University, Chengdu, 610064, China.
  • Zhang GH; College of Chemistry, Sichuan University, Chengdu, 610064, China.
  • Zhu QH; College of Chemistry, Sichuan University, Chengdu, 610064, China.
  • Wang SL; College of Chemistry, Sichuan University, Chengdu, 610064, China.
  • Qin S; College of Chemistry, Sichuan University, Chengdu, 610064, China.
  • He L; College of Chemistry, Sichuan University, Chengdu, 610064, China.
  • Tao GH; College of Chemistry, Sichuan University, Chengdu, 610064, China.
Small ; 19(39): e2302570, 2023 Sep.
Article in En | MEDLINE | ID: mdl-37229752
ABSTRACT
Adsorption, storage, and conversion of gases (e.g., carbon dioxide, hydrogen, and iodine) are the three critical topics in the field of clean energy and environmental mediation. Exploring new methods to prepare high-performance materials to improve gas adsorption is one of the most concerning topics in recent years. In this work, an ionic liquid solution process (ILSP), which can greatly improve the adsorption kinetic performance of covalent organic framework (COF) materials for gaseous iodine, is explored. Anionic COF TpPaSO3 H is modified by amino-triazolium cation through the ILSP method, which successfully makes the iodine adsorption kinetic performance (K80% rate) of ionic liquid (IL) modified COF AC4 tirmTpPaSO3 quintuple compared with the original COF. A series of experimental characterization and theoretical calculation results show that the improvement of adsorption kinetics is benefited from the increased weak interaction between the COF and iodine, due to the local charge separation of the COF skeleton caused by the substitution of protons by the bulky cations of ILs. This ILSP strategy has competitive help for COF materials in the field of gas adsorption, separation, or conversion, and is expected to expand and improve the application of COF materials in energy and environmental science.
Key words

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Small Journal subject: ENGENHARIA BIOMEDICA Year: 2023 Document type: Article Affiliation country: China Publication country: ALEMANHA / ALEMANIA / DE / DEUSTCHLAND / GERMANY

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Small Journal subject: ENGENHARIA BIOMEDICA Year: 2023 Document type: Article Affiliation country: China Publication country: ALEMANHA / ALEMANIA / DE / DEUSTCHLAND / GERMANY