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Pd/Cu-catalyzed cascade Heck-type reactions of alkenyl halides with terminal alkynes toward substituted pyrrolidine analogues.
Xu, Shiji; Wang, Qiang; Sun, Jing; Han, Ying; Hu, Weiming; Wang, Lei; Yan, Chao-Guo.
Affiliation
  • Xu S; School of Chemistry & Chemical Engineering, Yangzhou University, 225002, Yangzhou, P. R. China. lei.wang@yzu.edu.cn.
  • Wang Q; School of Chemistry & Chemical Engineering, Yangzhou University, 225002, Yangzhou, P. R. China. lei.wang@yzu.edu.cn.
  • Sun J; School of Chemistry & Chemical Engineering, Yangzhou University, 225002, Yangzhou, P. R. China. lei.wang@yzu.edu.cn.
  • Han Y; School of Chemistry & Chemical Engineering, Yangzhou University, 225002, Yangzhou, P. R. China. lei.wang@yzu.edu.cn.
  • Hu W; Jiangsu Key Laboratory of Function Control Technology for Advanced Materials, School of Environmental and Chemical Engineering, Jiangsu Ocean University, Lianyungang 222005, Jiangsu, China. huweiming@jou.edu.cn.
  • Wang L; School of Chemistry & Chemical Engineering, Yangzhou University, 225002, Yangzhou, P. R. China. lei.wang@yzu.edu.cn.
  • Yan CG; School of Chemistry & Chemical Engineering, Yangzhou University, 225002, Yangzhou, P. R. China. lei.wang@yzu.edu.cn.
Org Biomol Chem ; 21(28): 5742-5746, 2023 Jul 19.
Article in En | MEDLINE | ID: mdl-37401570
ABSTRACT
Pd/Cu-catalyzed cascade Heck-type reactions of alkenyl halides with terminal alkynes have been developed. This research provides an efficient atom-economical approach to access a variety of highly substituted pyrrolidines in moderate to good yields. This protocol features readily available substrates, broad substrate scope, easy scale-up, high selectivities and versatile transformations.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Biomol Chem Journal subject: BIOQUIMICA / QUIMICA Year: 2023 Document type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Biomol Chem Journal subject: BIOQUIMICA / QUIMICA Year: 2023 Document type: Article