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Pillar[5]arene-segregated ion pairs for enhanced cycloaddition of epoxides with CO2.
Zhou, Yidan; Liu, Zejiang; Yang, Zhiyao; Zheng, Yuexuan; Yang, Maoxia; Feng, Wen; Li, Xiaowei; Yuan, Lihua.
Affiliation
  • Zhou Y; College of Chemistry, Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu, 610064, China. lhyuan@scu.edu.cn.
  • Liu Z; College of Chemistry, Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu, 610064, China. lhyuan@scu.edu.cn.
  • Yang Z; College of Chemistry, Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu, 610064, China. lhyuan@scu.edu.cn.
  • Zheng Y; College of Chemistry, Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu, 610064, China. lhyuan@scu.edu.cn.
  • Yang M; College of Chemistry, Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu, 610064, China. lhyuan@scu.edu.cn.
  • Feng W; College of Chemistry, Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu, 610064, China. lhyuan@scu.edu.cn.
  • Li X; College of Chemistry, Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu, 610064, China. lhyuan@scu.edu.cn.
  • Yuan L; College of Chemistry, Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu, 610064, China. lhyuan@scu.edu.cn.
Chem Commun (Camb) ; 60(3): 300-303, 2024 Jan 02.
Article in En | MEDLINE | ID: mdl-38054763
ABSTRACT
A supramolecular approach using a polyviologen-pillar[5]arene complex as segregated ion pairs was shown to be highly efficient for the conversion of CO2 with epoxides into cyclic carbonates without the need for metals or solvents. The enhanced catalytic performance was achieved by cooperative ion pair segregation and CO2 fixation.

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: China Publication country: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: China Publication country: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM