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Contracted description of driven degenerate multilevel quantum systems.
Xu, Xiangyu; Sun, Kewei; Gelin, Maxim F; Zhao, Yang.
Affiliation
  • Xu X; School of Science, Hangzhou Dianzi University, Hangzhou 310018, China.
  • Sun K; School of Science, Hangzhou Dianzi University, Hangzhou 310018, China.
  • Gelin MF; School of Science, Hangzhou Dianzi University, Hangzhou 310018, China.
  • Zhao Y; School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore.
J Chem Phys ; 159(22)2023 Dec 14.
Article in En | MEDLINE | ID: mdl-38088431
ABSTRACT
We formulate a contraction theorem that maps quantum dynamics of a multilevel degenerate system (DS) driven by a time-dependent external field to the dynamics of the corresponding contracted non-degenerate system (CNS) of lower dimension, provided transitions between each pair of degenerate levels in the DS have identical transition dipole moments. The theorem is valid for an external field of any strength and shape, with and without rotating wave approximation in the system-field interaction. It establishes explicit relations between DS and CNS observables, significantly simplifies numerical calculations, and clarifies physical origins of the field-induced DS dynamics.

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Chem Phys Year: 2023 Document type: Article Affiliation country: China

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Chem Phys Year: 2023 Document type: Article Affiliation country: China