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Tunable cyclic operation of dissipative molecular switches based on anion recognition.
Zhang, Xin; Mao, Lijun; He, Rongjing; Shi, Yanting; Li, Lingyi; Li, Shuo; Zhu, Chenghao; Zhang, Yanjing; Ma, Da.
Affiliation
  • Zhang X; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
  • Mao L; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
  • He R; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
  • Shi Y; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
  • Li L; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
  • Li S; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
  • Zhu C; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
  • Zhang Y; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
  • Ma D; School of Pharmaceutical Engineering and Institute for Advanced Studies, Taizhou University, Taizhou 318000, China. dama@tzc.edu.cn.
Chem Commun (Camb) ; 60(9): 1180-1183, 2024 Jan 25.
Article in En | MEDLINE | ID: mdl-38193867
ABSTRACT
Artificial dissipative molecular switches based on anion recognition are of great importance to simulate biological functions and construct smart materials. Five activated carboxylic acids are used as chemical fuels for dissipative molecular switches, which consist of an imidazolium macrocyclic host and a carboxylate anionic guest. By choosing different types of chemical fuels and using varied fuel concentrations, the rates of cyclic operations are tunable. The operation is capable of undergoing at least three cycles.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: China Country of publication: United kingdom
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: China Country of publication: United kingdom