Gold Recovery from E-Waste by Food-Waste Amyloid Aerogels.

ABSTRACT

Demand for gold recovery from e-waste grows steadily due to its pervasive use in the most diverse technical applications. Current methods of gold recovery are resource-intensive, necessitating the development of more efficient extraction materials. This study explores protein amyloid nanofibrils (AF) derived from whey, a dairy industry side-stream, as a novel adsorbent for gold recovery from e-waste. To do so, AF aerogels are prepared and assessed against gold adsorption capacity and selectivity over other metals present in waste electrical and electronic equipment (e-waste). The results demonstrate that AF aerogel has a remarkable gold adsorption capacity (166.7 mg g-1) and selectivity, making it efficient and an adsorbent for gold recovery. Moreover, AF aerogels are efficient templates to convert gold ions into single crystalline flakes due to Au growth along the (111) plane. When used as templates to recover gold from e-waste solutions obtained by dissolving computer motherboards in suitable solvents, the process yields high-purity gold nuggets, constituted by ≈90.8 wt% gold (21-22 carats), with trace amounts of other metals. Life cycle assessment and techno-economic analysis of the process finally consolidate the potential of protein nanofibril aerogels from food side-streams as an environmentally friendly and economically viable approach for gold recovery from e-waste.