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Spodium bonding in bis(alkynyl)mecurials.
Onn, Chee S; Hill, Anthony F; Ward, Jas S.
Affiliation
  • Onn CS; Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, ACT 2601, Australia. a.hill@anu.edu.au.
  • Hill AF; Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, ACT 2601, Australia. a.hill@anu.edu.au.
  • Ward JS; Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, ACT 2601, Australia. a.hill@anu.edu.au.
Chem Commun (Camb) ; 60(18): 2552-2555, 2024 Feb 27.
Article in En | MEDLINE | ID: mdl-38343202
ABSTRACT
The new bis(alkynyl)mercurial Hg{CCSeCW(CO)2(Tp*)}2 (Tp* = tris(dimethylpyrazolyl)borate) forms adducts with fluoride and phenathroline, the structures of which are interpreted in the context of two-coordinate mercury presenting a σ-torroid for spodium bonding.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) / Chem. commun. (Lond., 1996, Online) / Chemical communications (London. 1996. Online) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: Australia Country of publication: United kingdom
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) / Chem. commun. (Lond., 1996, Online) / Chemical communications (London. 1996. Online) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: Australia Country of publication: United kingdom