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Strengthening the Metal-Acid Interactions by Using CeO2 as Regulators of Precisely Placing Pt Species in ZSM-5 for Furfural Hydrogenation.
Zhao, Meng; Wang, Xiao; Xu, Jing; Li, Yuou; Wang, Xiaomei; Chu, Xiang; Wang, Ke; Wang, Zijian; Zhang, Ling-Ling; Feng, Jing; Song, Shuyan; Zhang, Hongjie.
Affiliation
  • Zhao M; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China.
  • Wang X; School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei, 230026, China.
  • Xu J; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China.
  • Li Y; School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei, 230026, China.
  • Wang X; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China.
  • Chu X; School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei, 230026, China.
  • Wang K; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China.
  • Wang Z; School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei, 230026, China.
  • Zhang LL; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China.
  • Feng J; School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei, 230026, China.
  • Song S; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China.
  • Zhang H; School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei, 230026, China.
Adv Mater ; 36(21): e2313596, 2024 May.
Article in En | MEDLINE | ID: mdl-38408470
ABSTRACT
Understanding the synergism between the metal site and acid site is of great significance in boosting the efficiency of bi-functional catalysts in many heterogeneous reactions, particularly in biomass upgrading. Herein, a "confined auto-redox" strategy is reported to fix CeO2-anchored Pt atoms on the inner wall of a ZSM-5 cage, achieving the target of finely controlling the placements of the two active sites. Compared with the conventional surface-supported counterpart, the encapsulated Pt/CeO2@ZSM-5 catalyst possesses remarkably-improved activity and selectivity, which can convert >99% furfural into cyclopentanone with 97.2% selectivity in 6 h at 160 °C. Besides the excellent catalytic performance, the ordered metal-acid distribution also makes such kind of catalyst an ideal research subject for metal-acid interactions. The following mechanization investigation reveals that the enhancement is strongly related to the unique encapsulation structure, which promotes the migration of the reactants over different active sites, thereby contributing to the tandem reaction.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Adv Mater Journal subject: BIOFISICA / QUIMICA Year: 2024 Document type: Article Affiliation country: China
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Adv Mater Journal subject: BIOFISICA / QUIMICA Year: 2024 Document type: Article Affiliation country: China