Understanding seasonal variations in As and Pb river fluxes and their regulatory mechanisms through monitoring data.

ABSTRACT

The Doce River Basin (DRB) suffers with the adverse impacts of mining activities, due to its high level of urbanization and numerous industrial operations. In this study, we present novel insights into contaminant flow dynamics, seasonal variations, and the primary factors driving concentration levels within the region. We conducted an extensive analysis using a database sourced from the literature, which contained data on the contamination of arsenic (As) and lead (Pb) in the Doce River. Our primary aim was to investigate the patterns of As and Pb flow throughout the entire basin, their response to seasonal fluctuations, and the key parameters influencing their concentration levels. The results showed significant seasonal fluctuations in As and Pb fluxes, peaking during the rainy season. The 2015 Fundão dam breach in the DRB led to notable changes, elevating elemental concentrations, particularly As and Pb, which were subsequently transported to the Atlantic Ocean. These increased concentrations were primarily associated with iron and manganese oxides, hydroxides, and sulfates, rather than precipitation, as evidenced by regressions with low R2 values for both As (R2 = 0.07) and Pb (R2 < 0.001), concerning precipitation. The PCA analysis further supports the connection between these elements and the oxides and hydroxides of Fe and Mn. The approach employed in this study has proven to be highly effective in comprehending biogeochemical phenomena by leveraging data from the literature and could be a model for optimizing resources by capitalizing on existing information to provide valuable insights for drainage basin management, particularly during crises.