Your browser doesn't support javascript.
loading
Achieving Efficient Dark Blue Room-Temperature Phosphorescence with Ultra-Wide Range Tunable-Lifetime.
Zhou, Lei; Song, Jinming; He, Zhenyi; Liu, Yiwei; Jiang, Ping; Li, Tao; Ma, Xiang.
Affiliation
  • Zhou L; Key Laboratory for Advance Materials and Feringa Noble Prize Scientist Joint Research Centre, Frontiers Science for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Meilong Road 130, Shanghai, 200237, China.
  • Song J; Key Laboratory for Advance Materials and Feringa Noble Prize Scientist Joint Research Centre, Frontiers Science for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Meilong Road 130, Shanghai, 200237, China.
  • He Z; Key Laboratory for Advance Materials and Feringa Noble Prize Scientist Joint Research Centre, Frontiers Science for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Meilong Road 130, Shanghai, 200237, China.
  • Liu Y; Key Laboratory for Advance Materials and Feringa Noble Prize Scientist Joint Research Centre, Frontiers Science for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Meilong Road 130, Shanghai, 200237, China.
  • Jiang P; Key Laboratory for Advance Materials and Feringa Noble Prize Scientist Joint Research Centre, Frontiers Science for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Meilong Road 130, Shanghai, 200237, China.
  • Li T; Key Laboratory for Advance Materials and Feringa Noble Prize Scientist Joint Research Centre, Frontiers Science for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Meilong Road 130, Shanghai, 200237, China.
  • Ma X; Key Laboratory for Advance Materials and Feringa Noble Prize Scientist Joint Research Centre, Frontiers Science for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Meilong Road 130, Shanghai, 200237, China.
Angew Chem Int Ed Engl ; 63(22): e202403773, 2024 May 27.
Article in En | MEDLINE | ID: mdl-38527962
ABSTRACT
Tunable-lifetime room-temperature phosphorescence (RTP) materials have been widely studied due to their broad applications. However, only few reports have achieved wide-range lifetime modulation. In this work, ultra-wide range tunable-lifetime efficient dark blue RTP materials were realized by doping methyl benzoate derivatives into polyvinyl alcohol (PVA) matrix. The phosphorescence lifetimes of the doped films can be increased from 32.8 ms to 1925.8 ms. Such wide range of phosphorescence lifetime modulation is extremely rare in current reports. Moreover, the phosphorescence emission of the methyl 4-hydroxybenzoate-doped film is located in the dark blue region and the phosphorescence quantum yield reaches as high as 15.4 %, which broadens their applications in organic optoelectronic information. Further studies demonstrated that the reason for the tunable lifetime was that the magnitude of the electron-donating ability of the substituent group modulates the HOMO-LUMO and singlet-triplet energy gap of methyl benzoate derivatives, as well as the ability to non-covalent interactions with PVA. Moreover, the potential applications of luminescent displays and optical anti-counterfeiting of these high-performance dark blue RTP materials have been conducted.
Key words

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Angew Chem Int Ed Engl Year: 2024 Document type: Article Affiliation country: China

Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Angew Chem Int Ed Engl Year: 2024 Document type: Article Affiliation country: China