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Direct S0 → Tn Transition under Visible Light Irradiation Enabling Synthesis of a Pseudoindoxyl Scaffold.
Nakajima, Masaya; Nagasawa, Sho; Yamazaki, Keita; Yazawa, Tomohiro; Yoneyama, Honoka; Kotaka, Yuko; Nemoto, Tetsuhiro.
Affiliation
  • Nakajima M; Graduate School of Pharmaceutical Sciences, Chiba University, 1-8-1, Inohana, Chuo-ku, Chiba 260-8675, Japan.
  • Nagasawa S; Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
  • Yamazaki K; Graduate School of Pharmaceutical Sciences, Chiba University, 1-8-1, Inohana, Chuo-ku, Chiba 260-8675, Japan.
  • Yazawa T; Graduate School of Pharmaceutical Sciences, Chiba University, 1-8-1, Inohana, Chuo-ku, Chiba 260-8675, Japan.
  • Yoneyama H; Graduate School of Pharmaceutical Sciences, Chiba University, 1-8-1, Inohana, Chuo-ku, Chiba 260-8675, Japan.
  • Kotaka Y; Graduate School of Pharmaceutical Sciences, Chiba University, 1-8-1, Inohana, Chuo-ku, Chiba 260-8675, Japan.
  • Nemoto T; Graduate School of Pharmaceutical Sciences, Chiba University, 1-8-1, Inohana, Chuo-ku, Chiba 260-8675, Japan.
Org Lett ; 26(15): 3289-3293, 2024 Apr 19.
Article in En | MEDLINE | ID: mdl-38568017
ABSTRACT
Pseudoindoxyl is a partial skeleton found in various natural products. Its light-absorption properties make it useful for the design of functional molecules. However, versatile synthesis methods have not yet been reported. In this report, we present a versatile synthetic method for pseudoindoxyls using the direct S0 → Tn transition under visible light irradiation. We also discuss the application of pseudoindoxyls as photocatalysts.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Lett / Org. lett / Organic letters Journal subject: BIOQUIMICA Year: 2024 Document type: Article Affiliation country: Japan Country of publication: United States
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Lett / Org. lett / Organic letters Journal subject: BIOQUIMICA Year: 2024 Document type: Article Affiliation country: Japan Country of publication: United States