Characterization of the first Peacock-Weakley polyoxometalate containing a transplutonium element: curium bis-pentatungstate [Cm(W5O18)2]9.
Chem Commun (Camb)
; 60(47): 5999-6002, 2024 Jun 06.
Article
in En
| MEDLINE
| ID: mdl-38747262
ABSTRACT
Leveraging microgram-level techniques, we here present the first transplutonium bis-pentatungstate complex NaCs8Cm(W5O18)2·14H2O (CmW5). Single crystal XRD, Raman, and fluorescence characterization show significant differences relative to analogous lanthanide compounds. The study reveals the unsuspected impact of counterions on fluorescence and vibrational modes of the curium complex and its lanthanide counterparts.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2024
Document type:
Article
Affiliation country:
United States