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CsAlB3O6Cl: the rational construction of a KBBF-type structure with aligned 2∞[AlB3O6Cl] layers via introducing unprecedented [AlO3Cl] tetrahedra.
Liu, Haoran; Jiao, Jiahao; Tudi, Abudukadi; Liu, Qingyu; Yang, Zhihua; Pan, Shilie; Zhang, Min.
Affiliation
  • Liu H; Research Center for Crystal Materials, State Key Laboratory of Functional Materials and Devices for Special Environmental Conditions, Xinjiang Key Laboratory of Functional Crystal Materials, Xinjiang Technical Institute of Physics and Chemistry, CAS, 40-1 South Beijing Road, Urumqi 830011, China.
  • Jiao J; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China.
  • Tudi A; Research Center for Crystal Materials, State Key Laboratory of Functional Materials and Devices for Special Environmental Conditions, Xinjiang Key Laboratory of Functional Crystal Materials, Xinjiang Technical Institute of Physics and Chemistry, CAS, 40-1 South Beijing Road, Urumqi 830011, China.
  • Liu Q; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China.
  • Yang Z; Research Center for Crystal Materials, State Key Laboratory of Functional Materials and Devices for Special Environmental Conditions, Xinjiang Key Laboratory of Functional Crystal Materials, Xinjiang Technical Institute of Physics and Chemistry, CAS, 40-1 South Beijing Road, Urumqi 830011, China.
  • Pan S; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China.
  • Zhang M; Research Center for Crystal Materials, State Key Laboratory of Functional Materials and Devices for Special Environmental Conditions, Xinjiang Key Laboratory of Functional Crystal Materials, Xinjiang Technical Institute of Physics and Chemistry, CAS, 40-1 South Beijing Road, Urumqi 830011, China.
Chem Commun (Camb) ; 60(51): 6516-6519, 2024 Jun 20.
Article in En | MEDLINE | ID: mdl-38836308
ABSTRACT
The first chloroaluminoborate, CsAlB3O6Cl, with innovative AlO3Cl tetrahedra and a perfect planar arrangement of [B3O6] groups, was structurally designed and synthesized via chlorination of [AlO4] tetrahedra. Simultaneously, the smooth introduction of the [AlO3Cl] group into borates initiates the development of a chloroaluminoborate and greatly enriches the structural chemistry of aluminoborates.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: China Country of publication: United kingdom
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: China Country of publication: United kingdom