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Dinitrogen activation at chromium by photochemically induced CrII-C bond homolysis.
Duletski, Olivia L; Platz, Duncan; Pollock, Charlie J; Mosquera, Martín A; Arulsamy, Navamoney; Mock, Michael T.
Affiliation
  • Duletski OL; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, USA. michael.mock@montana.edu.
  • Platz D; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, USA. michael.mock@montana.edu.
  • Pollock CJ; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, USA. michael.mock@montana.edu.
  • Mosquera MA; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, USA. michael.mock@montana.edu.
  • Arulsamy N; Department of Chemistry, University of Wyoming, Laramie, WY, 82071, USA.
  • Mock MT; Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, USA. michael.mock@montana.edu.
Chem Commun (Camb) ; 60(55): 7029-7032, 2024 Jul 04.
Article in En | MEDLINE | ID: mdl-38894651
ABSTRACT
The synthesis of the organochromium(II) complexes [POCOPtBu]Cr(R) (R = p-Tol, Bn) is reported. Exposure of [POCOPtBu]Cr(Bn) to visible light promoted homolytic Cr-CBn bond cleavage and formed {[POCOPtBu]Cr}2(η1η1µ-N2) via a putative [POCOPtBu]Cr(I) species.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: United States
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: United States