Dinitrogen activation at chromium by photochemically induced CrII-C bond homolysis.
Chem Commun (Camb)
; 60(55): 7029-7032, 2024 Jul 04.
Article
in En
| MEDLINE
| ID: mdl-38894651
ABSTRACT
The synthesis of the organochromium(II) complexes [POCOPtBu]Cr(R) (R = p-Tol, Bn) is reported. Exposure of [POCOPtBu]Cr(Bn) to visible light promoted homolytic Cr-CBn bond cleavage and formed {[POCOPtBu]Cr}2(η1η1µ-N2) via a putative [POCOPtBu]Cr(I) species.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2024
Document type:
Article
Affiliation country:
United States