Ru(0)-catalysed synthesis of borylated polyene building blocks by cross-dimerisation toward cross-coupling.
Chem Commun (Camb)
; 60(60): 7672-7686, 2024 Jul 23.
Article
in En
| MEDLINE
| ID: mdl-38962873
ABSTRACT
Conjugated and non-conjugated polyenes are important substructures and are often found in biologically active compounds and natural products. Their preparation often needs multiple steps or iterative reactions and as a result, they have poor step economies. In this feature article, we show a new methodology to prepare these substructures by combinations of cross-dimerisation giving borylated polyenes and subsequent cross-coupling reactions. This divergent reaction strategy allows for the opportunity to access many bioactive compounds and natural products as well as some electronic materials.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Journal subject:
QUIMICA
Year:
2024
Document type:
Article
Affiliation country:
Japan