Properties of Fiber-Reinforced Geopolymer Mortar Using Coal Gangue and Aeolian Sand.

ABSTRACT

Geopolymers, as a novel cementitious material, exhibit typical brittle failure characteristics under stress. To mitigate this brittleness, fibers can be incorporated to enhance toughness. This study investigates the effects of varying polypropylene fiber (PPF) content and fiber length on the flowability, mechanical properties, and flexural toughness of coal gangue-based geopolymers. Microstructural changes and porosity variations within the Fiber-Reinforced Geopolymer Mortar(GMPF) matrix were observed using scanning electron microscope (SEM) and Low field NMR(LF-NMR) to elucidate the toughening mechanism of PPF-reinforced geopolymers. The introduction of fibers into the geopolymer matrix demonstrated an initial bridging effect in the viscous geopolymer slurry, with a 3.0 vol% fiber content reducing fluidity by 5.6%. Early mechanical properties of GMPF were enhanced with fiber addition; at 1.5 vol% fiber content and 15 mm length, the 3-day flexural and compressive strengths increased by 30.81% and 17.4%, respectively. Furthermore, polypropylene fibers significantly improved the matrix's flexural toughness, which showed an increasing trend with higher fiber content. At a 3.0 vol% fiber content, the flexural toughness index increased by 198.35%. The data indicated that a fiber length of 12 mm yielded the best toughening effect, with an 84.03% increase in the flexural toughness index. SEM observations revealed a strong interfacial bond between fibers and the matrix, with noticeable damage on the fiber surface due to frictional forces, and fiber pull-out being the predominant failure mode. Porosity testing results indicated that fiber incorporation substantially improved the internal pore structure of the matrix, reducing the median pore diameter of mesopores and converting mesopores to micropores. Additionally, the number of harmless and less harmful pores increased by 23.01%, while the number of more harmful pores decreased by 30.43%.