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Modulation of Fe-Fe distance and spin in diiron complexes using tetradentate ligands with different flanking donors.
Spielvogel, Kyle D; Campbell, Emily J; Chowdhury, Sabyasachi Roy; Benner, Florian; Demir, Selvan; Hatzis, Gillian P; Petras, Hayley R; Sembukuttiarachchige, Dunya; Shepherd, James J; Thomas, Christine M; Vlaisavljevich, Bess; Daly, Scott R.
Affiliation
  • Spielvogel KD; The University of Iowa, Department of Chemistry, E331 Chemistry Building, Iowa City, IA 52242, USA. scott-daly@uiowa.edu.
  • Campbell EJ; The University of Iowa, Department of Chemistry, E331 Chemistry Building, Iowa City, IA 52242, USA. scott-daly@uiowa.edu.
  • Chowdhury SR; The University of South Dakota, Department of Chemistry, 414 E Clark St., Vermillion SD, 57069, USA.
  • Benner F; Michigan State University, Department of Chemistry, 578 South Shaw Lane, East Lansing, Michigan 48824, USA.
  • Demir S; Michigan State University, Department of Chemistry, 578 South Shaw Lane, East Lansing, Michigan 48824, USA.
  • Hatzis GP; The Ohio State University, Department of Chemistry and Biochemistry, 100 West 18th Ave, Columbus, OH 43210, USA.
  • Petras HR; The University of Iowa, Department of Chemistry, E331 Chemistry Building, Iowa City, IA 52242, USA. scott-daly@uiowa.edu.
  • Sembukuttiarachchige D; The University of Iowa, Department of Chemistry, E331 Chemistry Building, Iowa City, IA 52242, USA. scott-daly@uiowa.edu.
  • Shepherd JJ; The University of Iowa, Department of Chemistry, E331 Chemistry Building, Iowa City, IA 52242, USA. scott-daly@uiowa.edu.
  • Thomas CM; The Ohio State University, Department of Chemistry and Biochemistry, 100 West 18th Ave, Columbus, OH 43210, USA.
  • Vlaisavljevich B; The University of Iowa, Department of Chemistry, E331 Chemistry Building, Iowa City, IA 52242, USA. scott-daly@uiowa.edu.
  • Daly SR; The University of South Dakota, Department of Chemistry, 414 E Clark St., Vermillion SD, 57069, USA.
Chem Commun (Camb) ; 60(64): 8399-8402, 2024 Aug 06.
Article in En | MEDLINE | ID: mdl-39028006
ABSTRACT
Here we report the synthesis and characterization of diiron complexes containing triaryl N4 and N2S2 ligands derived from o-phenylenediamine. The complexes display significant differences in Fe-Fe distances and magnetic properties that depend on the identity of the flanking NMe2 and SMe donor groups.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: United States Country of publication: United kingdom
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: United States Country of publication: United kingdom