Formulation and Optimization of Effective Oil Spill Dispersants Composed of Surface-Active Ionic Liquids and Nonionic Surfactants.

ABSTRACT

The use of chemical dispersants to remove oil spills in aquatic environments raises serious concerns, including heightened toxicity and limited biodegradability, which diminish their effectiveness. This study aimed to develop an environmentally friendly formulation by combining two nonionic surfactants (Tween 80, Span 80) with two surface-active ionic liquids (SAILs) 1-butyl-3-methylimidazolium lauroyl sarcosinate [Bmim][Lausar] and choline myristate [Cho][Mys], to remediate crude oil spill. The performance of the formulation was evaluated by its emulsion stability, surface tension, interfacial tension (IFT), and effectiveness. The toxicity and biodegradability of the formulation were also assessed to ensure their safe application in aquatic environments. The formulation (F9) exhibited the most stable emulsion, maintaining stability even after 5 h with a critical micelle concentration (CMC) of 3.52 mM. The efficiency of the formulation in dispersing various crude oils (Arab, Ratawi, and Doba) ranged from 70.12 to 93.72%. Acute toxicity tests conducted on zebrafish demonstrated that the formulation, with an LC50 value of 450 mg L-1, exhibited practically nontoxicity after 96 h. The formulation showed rapid biodegradability, exceeding 60% within a 28-day testing period. This research presents a promising approach for synthesizing the green formulation which can contribute to mitigating the environmental impacts of oil spills and enhancing the efficiency of cleanup operations.