Synthesis, crystal structure and Hirshfeld surface analysis of [1-(4-bromo-phen-yl)-1H-1,2,3-triazol-4-yl]methyl 2-(4-nitro-phen-oxy)acetate.
Acta Crystallogr E Crystallogr Commun
; 80(Pt 8): 910-912, 2024 Aug 01.
Article
in En
| MEDLINE
| ID: mdl-39108790
ABSTRACT
The title compound, C17H13BrN4O5, was synthesized by a Cu2Br2-catalysed Meldal-Sharpless reaction between 4-nitro-phen-oxy-acetic acid propargyl ether and para-bromo-phenyl-azide, and characterized by X-ray structure determination and 1H NMR spectroscopy. The mol-ecules, with a near-perpendicular orientation of the bromo-phenyl-triazole and nitro-phen-oxy-acetate fragments, are connected into a three-dimensional network by inter-molecular C-Hâ¯O and C-Hâ¯N hydrogen bonds (confirmed by Hirshfeld surface analysis), π-π and Br-π inter-actions.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Acta Crystallogr E Crystallogr Commun
Year:
2024
Document type:
Article
Affiliation country:
Uzbekistan