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Visible-Light-Promoted Reduction of Nitroarenes with Formate Salts as Reductants.
Wu, Jun-Yue; Wan, Yuan-Cui; Shao, Yu; Zhan, Le-Wu; Li, Bin-Dong; Hou, Jing.
Affiliation
  • Wu JY; Nanjing University of Science and Technology, Department of chemistry and chemical engineering, CHINA.
  • Wan YC; Nanjing University of Science and Technology, Department of chemistry and chemical engineering, CHINA.
  • Shao Y; Nanjing University of Science and Technology, Department of chemistry and chemical engineering, CHINA.
  • Zhan LW; Nanjing University of Science and Technology, Department of chemistry and chemical engineering, CHINA.
  • Li BD; Nanjing University of Science and Technology, Department of chemistry and chemical engineering, CHINA.
  • Hou J; Nanjing University of Science and Technology, Department of Pharmaceutical Engineering & Fine Chemistry, Xiao Ling Wei Street 200, Xuanwu District, 210094, Nanjing, CHINA.
Chemistry ; : e202402870, 2024 Sep 26.
Article in En | MEDLINE | ID: mdl-39324515
ABSTRACT
A visible-light-promoted reduction of nitrobenzenes using formate salts as the reductant was developed. A wide range of nitrobenzenes can be converted into aniline products in a transition metal free fashion. Mechanistic studies revealed that radical species (carbon dioxide radical anion and thiol radical) are key intermediates for the transformation. We anticipate that this method will provide a valuable and green strategy for the reduction of nitrobenzenes.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chemistry Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: China Country of publication: Germany
Fulltext
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chemistry Journal subject: QUIMICA Year: 2024 Document type: Article Affiliation country: China Country of publication: Germany