Palladium-catalyzed thio- and selenocarbonylation of 2-iodoglycals
ChemCatChem, v. 12, p. 576-583, jan. 2020
Article
en En
| SES-SP, SESSP-IBPROD, SES-SP
| ID: bud-3036
Biblioteca responsable:
BR78.1
ABSTRACT
The carbonylative cross-coupling reactions of 2-iodoglycals with thiols and selenols in the presence of molybdenum hexacarbonyl as a solid source of carbon monoxide is described. This methodology permitted the synthesis of 29 C2-glycosides bearing thioester and selenoester functionalities in moderate to excellent yields and high functional group tolerance. Moreover, this communication describes the first catalytic carbonylative coupling reaction of selenols with a carbon electrophile.
Texto completo:
1
Colección:
06-national
/
BR
Base de datos:
SES-SP
/
SESSP-IBPROD
Idioma:
En
Revista:
ChemCatChem
Año:
2020
Tipo del documento:
Article