[HPLC-separation of racemic cyclohexane-1,2-diamine platinum(II) dimyristates on chiral stationary phases] . / Zur Trennung racemischer Cyclohexan-1,2-diamin-Platin(II)-dimyristate durch HPLC an chiralen stationären Phasen.

ABSTRACT

In this paper, the stereochemical resolution of racemic cyclohexane-1,2-diamine platinum(II) dimyristates on chiral stationary phases (CSP) is described. These CSP are Pirkle phases chiral column (Sumichiral OA-2500, 3100, 3200, 3300, 4000, 4100). Among them, the Sumichiral OA-2500 column gave the best results. The effects of the temperature and mobile phase composition as well as the hydrophobicity of the analytes on the chromatographic separation are described.