m-CPBA/KOH: an efficient reagent for nucleophilic epoxidation of gem-deactivated olefins.
J Org Chem
; 70(11): 4300-6, 2005 May 27.
Article
en En
| MEDLINE
| ID: mdl-15903303
ABSTRACT
The m-chloroperoxybenzoate anion (generated from m-CPBA and bases such as K(2)CO(3) or KOH) is a highly efficient nucleophilic epoxidating reagent for strongly deactivated olefins containing two electron-withdrawing groups at the same carbon, under mild conditions which affect neither other double bonds nor electrophilic oxidizable centers such as sulfoxides.
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01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
J Org Chem
Año:
2005
Tipo del documento:
Article
País de afiliación:
España