Acyclic amino acid-catalyzed direct asymmetric aldol reactions: alanine, the simplest stereoselective organocatalyst.
Chem Commun (Camb)
; (28): 3586-8, 2005 Jul 28.
Article
en En
| MEDLINE
| ID: mdl-16010332
ABSTRACT
The linear amino acid-catalyzed direct asymmetric intermolecular aldol reaction is presented; simple amino acids such as alanine, valine, isoleucine, aspartate, alanine tetrazole and serine catalyzed the direct catalytic asymmetric intermolecular aldol reactions between unmodified ketones and aldehydes with excellent stereocontrol and furnished the corresponding aldol products in up to 98% yield and with up to > 99% ee.
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Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Catálisis
/
Alanina
/
Aminoácidos
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2005
Tipo del documento:
Article
País de afiliación:
Suecia