EPR spectroscopy of the manganese cluster of photosystem II.
Photosynth Res
; 92(3): 357-68, 2007 Jun.
Article
en En
| MEDLINE
| ID: mdl-17551843
ABSTRACT
Electron paramagnetic resonance (EPR) spectroscopy is a valuable tool for understanding the oxidation state and chemical environment of the Mn4Ca cluster of photosystem II. Since the discovery of the multiline signal from the S2 state, EPR spectroscopy has continued to reveal details about the catalytic center of oxygen evolution. At present EPR signals from nearly all of the S-states of the Mn4Ca cluster, as well as from modified and intermediate states, have been observed. This review article describes the various EPR signals obtained from the Mn4Ca cluster, including the metalloradical signals due to interaction of the cluster with a nearby organic radical.
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Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Espectroscopía de Resonancia por Spin del Electrón
/
Complejo de Proteína del Fotosistema II
/
Manganeso
Idioma:
En
Revista:
Photosynth Res
Asunto de la revista:
METABOLISMO
Año:
2007
Tipo del documento:
Article
País de afiliación:
Estados Unidos
Pais de publicación:
HOLANDA
/
HOLLAND
/
NETHERLANDS
/
NL
/
PAISES BAJOS
/
THE NETHERLANDS