Theoretical study of isomerization mechanisms in fluorinated fullerene derivatives.
J Phys Chem A
; 113(40): 10833-8, 2009 Oct 08.
Article
en En
| MEDLINE
| ID: mdl-19791814
ABSTRACT
Various candidate processes that can effect rearrangement of the shell of addends are being discussed for C(60)F(x) and C(60)(CF(3))(y) compounds. It is shown that isomerization of fluorofullerenes is catalyzed by other fullerene molecules or organic donors, while in trifluoromethylated fullerenes such catalysis is inefficient. These observations afford an explanation for important differences between fluorides and CF(3) derivatives of C(60) in distribution of products of their high-temperature syntheses.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Fulerenos
/
Fluorocarburos
/
Modelos Químicos
Idioma:
En
Revista:
J Phys Chem A
Asunto de la revista:
QUIMICA
Año:
2009
Tipo del documento:
Article
País de afiliación:
Rusia