One-dimensional supramolecular surface structures: 1,4-diisocyanobenzene on Au(111) surfaces.
Phys Chem Chem Phys
; 12(37): 11624-9, 2010 Oct 07.
Article
en En
| MEDLINE
| ID: mdl-20714484
ABSTRACT
One-dimensional supramolecular structures formed by adsorbing low coverages of 1,4-diisocyanobenzene on Au(111) at room temperature are obtained and imaged by scanning tunneling microscopy (STM) under ultrahigh vacuum (UHV) conditions. The structures originate from step edges or surface defects and arrange predominantly in a straight fashion on the substrate terraces along the <110> directions. They are proposed to consist of alternating units of 1,4-diisocyanobenzene molecules and gold atoms with a unit cell in registry with the substrate corresponding to four times the lattice interatomic distance. Their long 1-D chains and high thermal stability offer the potential to use them as conductors in nanoelectronic applications.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Derivados del Benceno
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Oro
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Nitrilos
Idioma:
En
Revista:
Phys Chem Chem Phys
Asunto de la revista:
BIOFISICA
/
QUIMICA
Año:
2010
Tipo del documento:
Article
País de afiliación:
Estados Unidos