Optimization of processing conditions for the fractionation of triticale straw using pressurized low polarity water.

ABSTRACT

Pressurized low polarity water (PLPW) fractionation of triticale straw was optimized to maximize hemicellulose and lignin yield, and to produce a cellulose rich fraction for biofuels production. The optimum PLPW conditions for hemicellulose yield was determined to be 165 °C, with a flow rate of 115 mL/min, and a solvent-to-solid ratio of 60 mL/g. Hemicellulose and lignin yield generally increased with increasing temperature and solvent-to-solid ratio. There was a small decrease in hemicellulose yield with an increase in flow rate. Minimum lignin content of the triticale straw residue after extraction was predicted to occur at a processing condition of 206 °C, 160 mL/min, and 67 mL/g. PLPW was successful in removing 73-78% of the hemicellulose, leaving a cellulose rich fraction (65% glucose concentration). Lignin was equally distributed between the solid residues and the extracts and most of the hemicellulose was extracted in oligomer form. Remaining solid residues after fractionation were highly digestible by cellulase enzymes.