Thermodynamics and micro heterogeneity of ionic liquids.
Top Curr Chem
; 290: 161-83, 2010.
Article
en En
| MEDLINE
| ID: mdl-21107797
ABSTRACT
The high degree of organisation in the fluid phase of room-temperature ionic liquids has major consequences on their macroscopic properties, namely on their behaviour as solvents. This nanoscale self-organisation is the result of an interplay between two types of interaction in the liquid phase - Coulomb and van der Waals - that eventually leads to the formation of medium-range structures and the recognition of some ionic liquids as composed of a high-charge density, cohesive network permeated by low-charge density regions.In this chapter, the structure of the ionic liquids will be explored and some of their consequences to the properties of ionic liquids analyzed.
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01-internacional
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MEDLINE
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Termodinámica
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Líquidos Iónicos
Idioma:
En
Revista:
Top Curr Chem
Año:
2010
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Article