Precise synthesis of molecularly defined oligomers and polymers by orthogonal iterative divergent/convergent approaches.
Macromol Rapid Commun
; 32(2): 147-68, 2011 Jan 17.
Article
en En
| MEDLINE
| ID: mdl-21433136
ABSTRACT
The synthesis of perfectly defined (macro)molecules has been a constant challenge for polymer and organic chemists. This paper highlights the main applications of the iterative divergent/convergent approach for the synthesis of discrete mass oligomers and polymers. We will discuss the orthogonal deprotection and coupling strategies involved in this powerful strategy where chain length doubles at each iteration and which has been applied to the synthesis of conjugated rigid rods as well as amorphous and crystalline oligomers and polymers. The synthesis of perfectly defined oligomers in respect to emerging highly efficient and orthogonal chemistries will also be highlighted.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Polímeros
/
Técnicas de Química Sintética
Idioma:
En
Revista:
Macromol Rapid Commun
Año:
2011
Tipo del documento:
Article
País de afiliación:
Australia