Dichlorido{N'-[1-(2-pyridin-2-yl)ethyl-idene]acetohydrazide-κN',O}copper(II).
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 1): m123, 2010 Dec 24.
Article
en En
| MEDLINE
| ID: mdl-21522534
ABSTRACT
In the title compound, [CuCl(2)(C(9)H(11)N(3)O)], the Cu(II) atom is in a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand chelates in a meridional fashion. The chloride ligand in the axial position forms a long Cu-Cl distance of 2.4892â
(9)â
Å. In contrast, the Cu-Cl distance from the equatorial chloride ligand is much shorter [2.2110â
(7)â
Å]. Inter-molecular N-Hâ¯Cl and C-Hâ¯Cl hydrogen bonds link the complexes into a three-dimensional network.
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01-internacional
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MEDLINE
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En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Año:
2010
Tipo del documento:
Article