Aqua-azido-{3,3'-[o-phenyl-enebis(nitrilo-methyl-idyne)]di-2-naphtholato}manganese(III).
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 1): m50, 2009 Dec 12.
Article
en En
| MEDLINE
| ID: mdl-21579948
ABSTRACT
In the title complex, [Mn(C(28)H(18)N(2)O(2))(N(3))(H(2)O)], the Mn(III) ion adopts a distorted fac-MnO(3)N(3) octa-hedral geometry arising from the O,N,N',O'-tetra-dentate Schiff base ligand, an azide ion and a water mol-ecule. In the crystal, inter-molecular O-Hâ¯(O,O) and O-Hâ¯N hydrogen bonds and π-π inter-actions [centroid-centroid separation = 3.5535â
(13)â
Å] link the mol-ecules into chains.
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01-internacional
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MEDLINE
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En
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Acta Crystallogr Sect E Struct Rep Online
Año:
2009
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Article