Piperidinium bis-(2-oxidobenzoato-κO,O)borate.
Acta Crystallogr Sect E Struct Rep Online
; 65(Pt 1): o171, 2008 Dec 20.
Article
en En
| MEDLINE
| ID: mdl-21581628
ABSTRACT
The asymmetric unit of the title compound, C(5)H(12)N(+)·C(14)H(8)BO(6) (-) or [C(5)H(12)N][BO(4)(C(7)H(4)O)(2)], contains two piperidinium cations and two bis-(salicylato)borate anions. The coordination geometries around the B atoms are distorted tetra-hedral. In the two mol-ecules, the aromatic rings are oriented at dihedral angles of 76.27â
(3) and 83.86â
(3)°. The rings containing B atoms have twist-boat conformations, while the two cations adopt chair conformations. In the crystal, the component species are linked by N-Hâ¯O hydrogen bonds. In the crystal structure, intra- and inter-molecular N-Hâ¯O hydrogen bonds link the mol-ecules.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Año:
2008
Tipo del documento:
Article