Bis(3-hydroxy-phenyl-acetato-κO,O')bis-(1H-imidazole-κN)nickel(II).
Acta Crystallogr Sect E Struct Rep Online
; 65(Pt 3): m330, 2009 Feb 28.
Article
en En
| MEDLINE
| ID: mdl-21582100
ABSTRACT
In the title mononuclear complex, [Ni(C(8)H(7)O(3))(2)(C(3)H(4)N(2))(2)], the Ni(II) atom, lying on a twofold rotation axis, is coordinated by four carboxyl-ate O atoms from two bidentate 3-hydroxy-phenylacetato ligands and two N atoms from two imidazole mol-ecules in a distorted octa-hedral geometry. A three-dimensional network is formed via inter-molecular O-Hâ¯O and N-Hâ¯O hydrogen bonds and π-π stacking inter-actions between the imidazole and benzene rings of neighboring mol-ecules [centroid-centroid distance = 3.856â
(2)â
Å].
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MEDLINE
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En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Año:
2009
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Article