Radiochemical neutron activation analysis for trace chlorine in steels and alloys.
Anal Chem
; 69(15): 3049-52, 1997 Aug 01.
Article
en En
| MEDLINE
| ID: mdl-21639324
ABSTRACT
Chlorine is usually present at low concentrations in reactor materials and thermal neutron activation of (35)Cl produces (36)Cl, which has a long half-life and is a radionuclide of significance in nuclear waste disposal. This paper describes a radiochemical method that has been developed to measure low concentrations of Cl in reactor stainless steels, so that the amount of (36)Cl in radioactive wastes can be estimated. The method is based on the irradiation of a 1 g sample in a thermal neutron flux of 10(16) n m(-)(2) s(-)(1), followed by dissolution in HNO(3) with the addition of stable KCl carrier/tracer. The Cl is precipitated as AgCl, and the recovery is measured gravimetrically. The (38)Cl, which has a half-life of 37 min, is measured with γ-ray spectrometry. The entire process, from irradiation to the end of counting, takes â¼1.5 h. The recovery is near-quantitative, and the detection limit for Cl in most stainless steels is below 1 mg/kg.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Anal Chem
Año:
1997
Tipo del documento:
Article
País de afiliación:
Reino Unido