N-heterocyclic carbene catalyzed direct carbonylation of dimethylamine.
Chem Commun (Camb)
; 47(27): 7860-2, 2011 Jul 21.
Article
en En
| MEDLINE
| ID: mdl-21643568
ABSTRACT
N-Heterocyclic carbene (NHC) catalyzed direct carbonylation of dimethylamine leading to the formation of DMF was successfully accomplished under metal-free conditions. The catalytic efficiency was investigated and the turnover numbers can reach as high as >300. The possible mechanism was also proposed.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2011
Tipo del documento:
Article