Structural modulation in the orbitally induced Peierls state of MgTi(2)O(4).
J Phys Condens Matter
; 20(27): 275230, 2008 Jul 09.
Article
en En
| MEDLINE
| ID: mdl-21694391
ABSTRACT
The structural properties associated with the orbitally induced Peierls transition in MgTi(2)O(4) are characterized by in situ cooling TEM observations. A distinctive structural modulation with the wavevector of q(1) = 1/4 (0, 0, 4) has been well demonstrated below a critical temperature of about 260 K for MgTi(2)O(4). Systematic analysis demonstrates that this structural modulation can be well explained by an orbital order existing in the low-temperature insulating phase. It is also noted that the nonstoichiometric feature commonly appearing in the present system could yield visible changes in both physical and structural properties. A low-temperature study of the microstructure of Mg[Ti(1.9)Mg(0.1)]O(4) reveals that a little substitution of Mg(2+) for Ti(3+) ions on the octahedral sites can disrupt the long-range order of the t(2g) orbitals, resulting in complex tweed structures in the superstructure phase.
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01-internacional
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MEDLINE
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En
Revista:
J Phys Condens Matter
Asunto de la revista:
BIOFISICA
Año:
2008
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Article