Synthesis of molybdenum alkylidene complexes that contain the 2,6-dimesitylphenylimido ligand.
J Am Chem Soc
; 133(45): 18142-4, 2011 Nov 16.
Article
en En
| MEDLINE
| ID: mdl-21999823
ABSTRACT
Compounds that have the formula M(NR)(CHR')(ORâ³)(Pyrrolide), where ORâ³ is "large" relative to NR and M = Mo or W, have been shown to be Z-selective olefin metathesis catalysts. In this communication we report a new route to Mo complexes in which the relationship between NR and ORâ³ has been reversed; i.e., the imido ligand is the sterically demanding 2,6-dimesitylphenylimido ligand (NAr*).
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Compuestos Organometálicos
/
Alquenos
/
Imidas
/
Molibdeno
Idioma:
En
Revista:
J Am Chem Soc
Año:
2011
Tipo del documento:
Article
País de afiliación:
Estados Unidos