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Poly[bis-[µ-1,4-bis-(imidazol-1-ylmeth-yl)benzene]-dichloridomanganese(II)].
Mei, Chong-Zhen; Shan, Wen-Wen; Li, Kai-Hui.
Afiliación
  • Mei CZ; North China University of Water Conservancy and Electric Power, Zhengzhou 450011, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online ; 67(Pt 8): m1156, 2011 Aug 01.
Article en En | MEDLINE | ID: mdl-22090913
In the crystal structure of the title compound, [MnCl(2)(C(14)H(14)N(4))(2)](n), the Mn(II) atom, lying on an inversion center, is coordinated by four N atoms from four 1,4-bis-(imidazol-1-ylmeth-yl)benzene (bimb) ligands and two Cl(-) anions in a distorted octa-hedral geometry. The bimb ligands bridge the Mn(II) atoms, forming a two-dimensional polymeric complex, which is composed of a 52-membered [Mn(4)(bimb)(4)] ring with distances of 7.7812 (2) and 27.4731 (9) Šbetween opposite metal atoms. Weak C-H⋯π inter-actions are present in the crystal structure.

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr Sect E Struct Rep Online Año: 2011 Tipo del documento: Article Pais de publicación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Acta Crystallogr Sect E Struct Rep Online Año: 2011 Tipo del documento: Article Pais de publicación: Estados Unidos