Design of main-chain polymers of chiral imidazolidinone for asymmetric organocatalysis application.

Haraguchi, Naoki; Kiyono, Hitomi; Takemura, Yu; Itsuno, Shinichi

Haraguchi, Naoki; Kiyono, Hitomi; Takemura, Yu; Itsuno, Shinichi.

Afiliación

Haraguchi N; haraguchi@ens.tut.ac.jp

Chem Commun (Camb) ; 48(33): 4011-3, 2012 Apr 25.

Article en En | MEDLINE | ID: mdl-22422078

ABSTRACT

ABSTRACT

Main-chain polymers of chiral imidazolidinone were successfully synthesized by reaction of chiral imidazolidinone dimers with disulfonic acid. Chiral imidazolidinones were incorporated into the main-chain of the polymer by ionic bonding. These polymers could be used as polymeric chiral organocatalysts for asymmetric Diels-Alder reactions.

Asunto(s)

Diseño de Fármacos; Imidazolidinas/química; Polímeros/química; Catálisis; Polímeros/síntesis química; Estereoisomerismo; Ácidos Sulfónicos/química

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Polímeros / Diseño de Fármacos / Imidazolidinas Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2012 Tipo del documento: Article

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