Diastereoselective alkylation reactions of 1-methylcyclohexa-2,5-diene-1-carboxylic acid.
Org Biomol Chem
; 10(19): 3859-65, 2012 May 21.
Article
en En
| MEDLINE
| ID: mdl-22473327
ABSTRACT
The deprotonation and alkylation of 1-methylcyclohexa-2,5-diene-1-carboxylic acid has been investigated under a range of conditions. In all cases, the formation of compounds 14 was found to be completely stereoselective, although compound 14c was formed as an impurity when alkyl iodides were used as electrophiles, and doubly-alkylated compounds 17 were formed in some cases when alkyl bromides were used.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Ácidos Ciclohexanocarboxílicos
Idioma:
En
Revista:
Org Biomol Chem
Asunto de la revista:
BIOQUIMICA
/
QUIMICA
Año:
2012
Tipo del documento:
Article
País de afiliación:
Reino Unido