α-Selective organocatalytic synthesis of 2-deoxygalactosides.
Angew Chem Int Ed Engl
; 51(36): 9152-5, 2012 Sep 03.
Article
en En
| MEDLINE
| ID: mdl-22887611
ABSTRACT
Alpha rules A thiourea acts as an efficient organocatalyst for the glycosylation of protected galactals to form oligosaccharides containing a 2-deoxymonosaccharide moiety. The reaction is highly stereoselective for α-linkages and proceeds by way of a syn-addition mechanism.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Tiourea
/
Galactósidos
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Año:
2012
Tipo del documento:
Article
País de afiliación:
Reino Unido
