Poly[[µ-(3-amino-pyridine)-κ(2)N:N'-µ-chlorido-chlorido(N,N'-dimethyl-formamide-κO)nickel(II)] N,N'-dimethyl-formamide monosolvate].
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 9): m1204-5, 2012 Sep 01.
Article
en En
| MEDLINE
| ID: mdl-22969491
The title compound, {[NiCl(2)(C(5)H(6)N(2))(C(3)H(7)NO)]·C(3)H(7)NO}(n), is a two-dimensional polymer in which the Ni(II) atom is coordinated by two N atoms from two 3-amino-pyridine ligands, one O atom from a dimethyl-formamide (DMF) group, one terminal Cl and two bridging Cl atoms in a distorted octa-hedral geometry. The Ni(II) atoms are bridged by the 3-amino-pyridine ligands [Niâ¯N = 6.7048â
(3)â
Å] and Cl(-) atoms [Niâ¯N = 3.5698â
(3)â
Å], forming (4,4) two-dimensional nets. The DMF solvent mol-ecule and the non-bridged Cl(-) ions participate in N-Hâ¯O and N-Hâ¯Cl hydrogen bonds with the amino groups.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Año:
2012
Tipo del documento:
Article
Pais de publicación:
Estados Unidos