Spin-active metallofullerene stabilized by the core of an NC moiety.

Feng, Yongqiang; Wang, Taishan; Wu, Jingyi; Ma, Yihan; Zhang, Zhuxia; Jiang, Li; Ge, Chunhua; Shu, Chunying; Wang, Chunru

Feng, Yongqiang; Wang, Taishan; Wu, Jingyi; Ma, Yihan; Zhang, Zhuxia; Jiang, Li; Ge, Chunhua; Shu, Chunying; Wang, Chunru.

Afiliación

Feng Y; Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.

Chem Commun (Camb) ; 49(21): 2148-50, 2013 Mar 14.

Article en En | MEDLINE | ID: mdl-23389116

ABSTRACT

ABSTRACT

A paramagnetic Sc(3)NC@C(80) anion radical was obtained by chemical reduction. ESR spectrometry and theoretical calculations disclosed that the core NC moiety takes possession of the unpaired electron and stabilizes the paramagnetic species. It is the first time a paramagnetic metal cyanide metallofullerene has been obtained.

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2013 Tipo del documento: Article País de afiliación: China

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