cis-Dichlorido(dimethyl sulfoxide-κS)(N,N,N',N'-tetra-methyl-guanidine-κN'')platinum(II).
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 2): m117-8, 2013 Feb 01.
Article
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| MEDLINE
| ID: mdl-23424410
In the title compound, cis-[PtCl(2)(C(5)H(13)N(3))(C(2)H(6)OS)], the four-coordinate Pt(II) atom is bonded to one N atom of the N,N,N',N'-tetra-methyl-guanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry. The bond lengths and angles of the N-Pt-Cl functionality are typical for imine dichloridoplatinum(II) complexes. The H atom of the imino group is oriented towards the O atom of the sulfoxide group of a neighboring mol-ecule and forms an N-Hâ¯O hydrogen bond.
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01-internacional
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MEDLINE
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En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Año:
2013
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Article
Pais de publicación:
Estados Unidos