Stimuli-responsive supramolecular gels through hierarchical self-assembly of discrete rhomboidal metallacycles.
Chemistry
; 19(31): 10094-100, 2013 Jul 29.
Article
en En
| MEDLINE
| ID: mdl-23843226
ABSTRACT
A new class of supramolecular organometallic gels with a discrete rhomboidal metallacycle as the main skeleton was fabricated through hierarchical self-assembly (see figure). More importantly, by taking advantage of the dynamic nature of metal-ligand bonds, the stimuli-responsive gel-sol transition of the obtained gels was realized by disassembly and reassembly of the rhomboidal scaffold as controlled by bromide anions.
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1
Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Chemistry
Asunto de la revista:
QUIMICA
Año:
2013
Tipo del documento:
Article