Organosilicon linkers in metal organic frameworks: the tetrahedral tetrakis(4-tetrazolylphenyl)silane ligand.
Dalton Trans
; 42(38): 13806-8, 2013 Oct 14.
Article
en En
| MEDLINE
| ID: mdl-23959136
ABSTRACT
Formal substitution of the central carbon by silicon within the tetrahedral tetrakis(4-tetrazolylphenyl)methane linker in a copper-based MOF is shown to uniquely influence the structure of the resultant MOF, affecting the orientation of the metal-based nodes and leading to an increase in unit-cell volume and solvent accessible void space.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Compuestos Organometálicos
/
Silanos
/
Tetrazoles
/
Cobre
Idioma:
En
Revista:
Dalton Trans
Asunto de la revista:
QUIMICA
Año:
2013
Tipo del documento:
Article
País de afiliación:
Reino Unido