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Redox-controlled δ-Dawson {Mn2(III)W17} polyoxometalate with photocatalytic H2 evolution activity.
Jiao, Yan-Qing; Qin, Chao; Wang, Xin-Long; Liu, Fu-Hong; Huang, Peng; Wang, Chun-Gang; Shao, Kui-Zhan; Su, Zhong-Min.
Afiliación
  • Jiao YQ; Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China. zmsu@nenu.edu.cn.
Chem Commun (Camb) ; 50(45): 5961-3, 2014 Jun 07.
Article en En | MEDLINE | ID: mdl-24525489
ABSTRACT
A novel δ-Dawson [(WO5)3W14Mn2(III)O44Cl2](12-) compound induced by the Jahn-Teller distortion of Mn(III) has been synthesized through utilizing {Mn12} as a reactant, which exhibits photocatalytic H2 evolution activity. Its electrochemical behavior and magnetic properties were investigated.
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2014 Tipo del documento: Article
Texto completo
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2014 Tipo del documento: Article